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LSR
2020/4/14   

LIQUID SILICONE RUBBER

& THERMOPLASTIC ELASTOMERS

LSR/LIM (Liquid Silicone Rubber /Liquid Injection Molding)

  • o   LSR’s developed in early 1970’s, and in the late 1970’s a “pumpable” silicone rubber was developed and available to fabricators.

  • o   Raw Material comes from one of earths elements- Silicon (a ROCK).

  • o   Liquid Injection Molded Liquid Silicone Rubbers involves lower viscosity two component flowablepastes with typical viscosities from 10,000 to 1,000,000 cps.

  • o   Two components (“A” & “B”) are kept separate and have extended shelf lives (6-months to years) if kept in closed containers.

  • o   RTV’s and LIM are part of NPI core technology.



5 Silicone Families

  1. 1. RTV’s (Room Temperature Vulcanizing)
  2. 2. Silanesand Coatings
  3. 3. Silicone Fluids
  4. 4. Silicone Sealants
  5. 5. Silicone Elastomers (LSR/LIM)


Types of LSR

Medical LSR

  • o   FDA Regulated

  • o   Critical long term implants

  • o   More than 29-day contact

  • o   Qualified lot-to-lot testing

  • o   Tested by material suppliers & manufacturers


Health Care LSR

o   Class VI Elastomers

o   Injection Moldable

o   Medical devices, wound care, body contact & Implantation up to 29-days

o   Dow Corning C6 and Q7, NuSil MED and many others


High End LSR

o   Fluoro silicone

o   Injection moldable, under hood applications

o   Withstand hot oils contact

o   Dow Corning FL - 40, WacherFLR & others


Optical LSR

o   LED, Solar, focusing optics

o   Castable, pourable, compression moldable, barely injection moldable

o   Encapsulant

o   Excellent for high heat, resists UV

Characteristics of LSR

 

Biocompatibility: Under extensive testing, liquid silicone rubber has demonstrated superior compatibility with human tissue and body fluids. In comparison to other elastomers, LSR is resistant to bacteria growth and will not stain or corrode other materials. LSR is also tasteless and odorless and can be formulated to comply with stringent FDA requirements. The material can be sterilized via a variety of methods, including steam autoclaving, ethylene oxide (ETO), gamma, e-beam and numerous other techniques, meeting all required approvals such as BfR XV, FDA 21 CFR 177.2600, USP Class VI.

Durable: LSR parts can withstand extreme temperatures, which makes them an ideal choice for components under the hood of cars and in close proximity to engines. Parts fabricated via liquid silicone rubber injection molding are fire retardant and will not melt.

Chemical resistance: Liquid silicone rubber resists water, oxidation and some chemical solutions such as acids and alkali.

Chemical resistance: Liquid silicone rubber resists water, oxidation and some chemical solutions such as acids and alkali.

Mechanical properties: LSR has good elongation, high tear and tensile strength, excellent flexibility and a hardness range of 5 to 80 Shore A.

Electrical properties: LSR has excellent insulating properties, which offer an appealing option for a host of electrical applications. Compared to conventional insulating material, silicone can perform in far higher and lower temperatures.

Transparency and pigmentation: LSR possesses a natural transparency, this attribute makes it possible to produce, colorful, custom, molded products

 

“Part A + Part B” Kit Sizes

  • o   55-Gallon Drums

  • o   5-Gallon Pails

  • o   Gallons, Quarts and pints.

  • o   Side by Side Cartridge sets.

  • o   Non 1:1 Ratio (100:1 to 1:100)

Mixing/ Feeding Systems

  • o   55 Gallon Drum Pump

  • o   5 Gallon Pump

  • o   Cartridge Pump

o   Prototype Mixing System


 LSR Molds

1.    Prototype

o   NPI: Custom heated master frame and insert system

           Vacuum venting is standard, “plaque mold”

o   Kipe Frame: Custom heated master frame & insert system build by KIPE Molds.

     Vacuum venting is possible

o   M.U.D. (Master Unit Die) Built from standard size

           Components purchased from catalogs

           Vacuum venting only with difficulty

           Not flash free & requires trimming


2. Production

o   Runner less :Uses pneumatic valve gate

o   Vacuum venting standard (if required)



LSR Equipment

 



Working process

LSR vs TPE

o    4 Families of TPE’s

o    TPO (Thermoplastic Olefin)- Ren flux

o    SBC (Styrene Block Co-polymer)- Krypton

o    TVP (Thermoplastic Vulcanizate)- Santoprene

o    E-TPE (Co-polyester Thermoplastic Elastomer)- Hytrel, Arnitel

o    Blend of plastics and rubbers.

o    Melt process- (add heat to soften, form and then cool to remove part).

o    Limitations:

- Not for high heat or extreme cold applications

- Not inherently UV stable

- Need to follow conventional good plastic part design guidelines

Advantages:

-Reasonable wall thicknesses

-Cored uniform wall thickness

-No sharp corners

-Gradual transition from thick to thin thickness

LSR

5 Families of LSR

o    Commercial- Silastic RBL-2004, KEG-2000, LR-3003

o    Healthcare- C6-XXXX, Q7-XXXX

o    Medical-MED-XXXX

o    High End- FL 40-9201

o    Optical- OE-6003, SR-7010, SCR-5001L-2

o    Thermoset: Mix & keep cool

o    Heat and time determine cure

o    Inject to form and heat to “cure” the part; temperature, part thickness, and time determine cycle

o    Material crosslink's, heat accelerates the process

o    Standard and custom colors readily available

Advantages:

o    Heat and cold resistant

o    UV stable; good for outdoor applications

o    Can form thick wall sections and abrupt wall thickness transitions

o    Batches stability (ready-to-use material)

o    Process repeatability

o    Direct injection (no waste)

o    Short cycle time

o    ‘free-flash’ technology (no burrs)

o    Automated process

o    Automated demolding systems

Key Terms

o    Elastomer- is a Polymer with the property of Elasticity- generally having notably

             Low Stiffness and high flexibility compared with other materials.

               TPE’s, LSR’s and Rubbers are all Elastomers.

o    Thermoplastic Elastomers (TPE) are similar to plastics- akin to softening butter. Should be defined by brand and grade (i.e. QST Monprene MP-2730, color Optional).

o    LSR is a thermoset Elastomer should be defined by group and hardness (i.e. Commercial 60 shore A) and ideally by brand (Momentive, Dow Corning, Wacker, ShinEtsu),and Grade Number (KEG-2000 60 Shore A).

.

Typical applications

Typical applications for liquid silicone rubber are products that require high precision such as

o    seals

o    sealing membranes

o    Electric connectors

o    multi-pin connectors,

 Infant products where smooth surfaces are desired, such as

o    Bottle nipples,

o    Medical applications as well as kitchen goods such as baking pans, spatulas, etc.

Often, silicone rubber is over molded onto other parts made of different plastics. For example, a silicone button face might be over molded onto an nylon66 housing.



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